structurally chiral

نویسنده

  • Akhlesh Lakhtakia
چکیده

In the Kretschmann configuration, the bulk metal is in the form of a thin film of uniform thickness, bounded on one side by a high–refractive–index dielectric material and on the other side by a low–refractive–index dielectric material. A plane wave is launched in the optically denser dielectric material towards the metal film, in order to excite a surface–plasmon wave at the interface of the metal with the optically rarer dielectric material [3]. The plane wave must be p–polarized, The telltale sign is a sharp peak in absorbance (i.e., a sharp trough in reflectance without a compensatory peak in transmittance) as the angle of incidence (with respect to the thickness direction) of the launched plane wave is changed [4]. Because the angle of incidence for exciting the surface–plasmon wave is a delicate function of the constitutive properties of all three materials, surface–plasmon waves in the visible and the near–infrared regimes are exploited for sensing, imaging, and other applications [5, 6].

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Optical crossover phenomenon due to a central 908-twist defect in a chiral sculptured thin film or chiral liquid crystal

We present a theoretical analysis of a remarkable phenomenon evinced by a periodic structurally chiral material—for example, a chiral sculptured thin film (STF) or a chiral liquid crystal—with a central 908-twist defect illuminated with normally incident, circularly polarized light. Based on the coupled-wave theory (CWT), an approximate but closed-form solution of the relevant boundary-value pr...

متن کامل

Narrowband and ultranarrowband filters with electro–optic structurally chiral materials

When a circularly polarized plane wave is normally incident on a slab of a structurally chiral material with local 4̄2m point group symmetry and a central twist defect, the slab can function as either a narrowband reflection hole filter for co–handed plane waves or an ultranarrowband transmission hole filter for cross–handed plane waves, depending on its thickness and the magnitude of the applie...

متن کامل

Targeted Chiral Analysis of Bioactive Arachidonic Acid Metabolites Using Liquid-Chromatography-Mass Spectrometry

A complex structurally diverse series of eicosanoids arises from the metabolism of arachidonic acid. The metabolic profile is further complicated by the enantioselectivity of eicosanoid formation and the variety of regioisomers that arise. In order to investigate the metabolism of arachidonic acid in vitro or in vivo, targeted methods are advantageous in order to distinguish between the complex...

متن کامل

Structurally perturbed chiral Bragg reflectors for elliptically polarized light.

The structure of an inorganic chiral medium represented as a stack of identical form-birefringent layers that twist steadily with increasing thickness is perturbed by realigning a fraction of each layer to a fixed direction. Experimental results show that the resulting chiral-birefringent composite medium exhibits Bragg resonance with elliptically polarized light, and simulations indicate that ...

متن کامل

Pyridinyloxazolidines: versatile scaffolds for chiral catalyst construction.

Pyridinyloxazolidines are structurally versatile chiral ligand frameworks that are easily made and coordinated to Pd(II); the resulting complexes, which show significant steric and electronic differences from their oxazoline counterparts, as well as intermolecular H-bonding in the solid state, can be isolated in diastereomerically pure form and are remarkably resistant to hydrolysis.

متن کامل

C(2)-symmetric chiral tetrathiafulvalene-bis(oxazolines) (TTF-BOX): new precursors for organic materials and electroactive metal complexes.

Chiral C(2)-symmetric electroactive bis(oxazolines) containing an EDT-TTF (ethylenedithio-tetrathiafulvalene) backbone, as promising multifunctional ligands and precursors for chiral molecular materials, were synthesized and structurally characterized, together with octahedral molybdenum and tungsten carbonyl complexes.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2008